Van Dijk will be serving his suspension after receiving a straight red card against Newcastle last weekend, while Ibrahima Konate is still a major doubt for the game, after picking up a muscle injury and missing the clash against the Magpies.
This means Liverpool will likely start Joel Matip and Joe Gomez at the back, but with Jarell Quansah's assured cameo, Jurgen Klopp will, at least, have a third option available to pick if he sees fit.
Curtis Jones and Thiago Alcantara were another two to miss out on the match day squad last weekend, with both midfielders recovering from respective injuries. The latest news is that both players are close to returning, but their involvement will depend on training across the week.
Stefan Bajcetic is the final question mark. The teenager featured on the bench against Newcastle, after spending a long time on the sidelines. Liverpool fans will be hoping the Spaniard finally steps foot back on the pitch on Sunday, but any involvement would likely be as a substitute, as he continues to regain match fitness.
Up front, Klopp admitted Nuñez had made a pretty good case for starting against Villa, but it remains to be seen if he'll get the nod ahead of Diogo Jota and Cody Gakpo.
With the summer transfer window closing on Friday, there could yet be a new name (or names) in the Liverpool squad come Sunday.
ASTON VILLA TEAM NEWS
Ahead of Sunday's game, Emery will be without an abundance of first team stars. Philippe Coutinho, Alex Moreno, and Jacob Ramsey will all miss out, while Tyrone Mings and Emi Buendia are both facing lengthy spells on the sidelines after picking up injuries earlier this season.
Meanwhile, Emi Martinez is also a doubt. The Argentinian shot stopper was substituted during Villa's 5-0 European win against Hibernian last week and subsequently missed out on last weekend's 3-1 victory against Burnley. Whether the keeper is fit enough to face Liverpool on Sunday remains to be seen.
Leander Dendoncker is another name that has been missing for Villa, with the Belgian missing the entirety of pre-season and all three opening fixtures in the Premier League. The midfielder is due to return to training this week, however, but it is doubtful that he would be fit enough to feature against the Reds.
PREDICTED LINEUP
Here's how Liverpool could start the game against Aston Villa on Sunday afternoon:
(4-3-3): Alisson Becker; Trent Alexander-Arnold, Joe Gomez, Joel Matip, Andy Robertson; Wataru Endo, Alexis Mac Allister, Dominik Szoboszlai; Mohamed Salah, Luis Diaz, Darwin Nuñez
PREDICTION
A game against an Emery side is never an easy task, and even with a plethora of injury concerns, Aston Villa have an incredibly strong squad this season.
However, Liverpool have already overcome Chelsea and Newcastle in difficult circumstances this season, and with the Anfield bounce, they should hopefully make it three wins from four.
Liverpool 3-1 Aston Villa
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